Ketones that have at least one alpha-hydrogen, undergo keto-enol tautomerization; the tautomer is an enol.Tautomerization is catalyzed by both acids and bases. Usually, the keto form is more stable than the enol. This equilibrium allows ketones to be prepared via the hydration of alkynes.. Acid/base properties of ketones. Ketones are far more acidic (pK a ≈ 20) than a regular alkane (pK a
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